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  Do we have a fundamental Hamiltonian for the system of H$_2$O molecules?

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From the quantum mechanics(QM) viewpoint, does there exist a Hamiltonian $H$ for the system of H$_2$O molecules? Assume that the number of H$_2$O molecules is fixed.

Imagine that by calculating the free energy $F(T)$ from the Hamiltonian $H$, one can reproduce the three common phases ice, water, and steam at different temperatures $T$(Here do we need order parameters to characterize these phases?). On the other hand, the Hamiltonian $H$ may depend on some parameters, i.e., $H=H(\lambda )$, and at $T=273K$, varying the parameter $\lambda $ causes the phase transition between ice and water without temperature changing.

So can we write a microscopic Hamiltonian $H$ of this kind in terms of the QM language?

This post imported from StackExchange Physics at 2014-03-09 08:38 (UCT), posted by SE-user K-boy
asked Dec 27, 2013 in Theoretical Physics by Kai Li (980 points) [ no revision ]

1 Answer

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From the quantum mechanics(QM) viewpoint, does there exist a Hamiltonian H for the system of H2O molecules? Assume that the number of H2O molecules is fixed.

Yes, the multi-particle Hamiltonian with the Coulomb potential energy. But calculating the free energy $F(T,V,N)$ from such Hamiltonian, although straightforward in principle, would be mathematically $very$ difficult.

How much gaseous, liquid and solid phase is present at the triple point is not determined by any parameter $\lambda$ in the microscopic Hamiltonian; it is rather part of the macroscopic description, similarly to volume $V$ and molar number $N$.

I do not know of approach that would describe water by free energy function(al) that uses order parameter (similar to Landau theory of magnetism). The Landau theory was meant for second-order phase transitions ; it does not seem to make sense for first-order transition that water may undergo at the triple point.

This post imported from StackExchange Physics at 2014-03-09 08:38 (UCT), posted by SE-user Ján Lalinský
answered Dec 27, 2013 by Ján Lalinský (10 points) [ no revision ]

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